Solução De N- Óxido De 4-Metilmorfolina , 50 P. % Em H 2 O, C/ 1000Gr

elated Categories	Chemical Synthesis, Other Oxidizing Agents, Oxidizing Agents, Synthetic Reagents
InChI Key	LFTLOKWAGJYHHR-UHFFFAOYSA-N
concentration	50 wt. % in H2O
refractive index	n20/D 1.4201
pH	9.00 ( in neat)
bp	118.5 °C
mp	-20 °C
density	1.13 g/mL at 25 °C
storage temp.	2-8°C

Packaging

1 kg in glass bottle

100 g in glass bottle

Application

• 4-Methylmorpholine N-oxide (NMO) is widely used as a co-oxidant to regenerate osmium tetroxide (OsO₄) catalyst during dihydroxylation of alkenes.^[1][2]
• In the presence of catalytic amounts of tetra-n-propylammonium perruthenate (TPAP), NMO oxidizes secondary amines to the corresponding imines.^[3]
• 4-Methylmorpholine N-oxide solution can be used to oxidize activated primary halides to aldehydes and secondary halides to ketones, respectively.^[4]
• It can also be used to promote stereoselective intermolecular Pauson-Khand reaction for the synthesis of cyclopentenones.^[5]

Oxidant for synthesis of novel organic polymer - inorganic hybrid for use as a catalyst for asymmetrical epoxidation

Reagent or Reactant for: 
• Cyclocondensation and cyclization in the enantioselective synthesis of oxazolomycin A
• Wharton rearrangement and stereoselective dihydroxylation reactions
• Reduction of amine N-oxides by diboron reagents
• Synthesis of polysaccharide blend fibers
• Synthesis of cellulose / modified nano-SiO2 composite packaging films
• Copper-catalyzed oxidative coupling for preparation of propargylamines

Used as

• CAS Number 7529-22-8

   

• Empirical Formula (Hill Notation) C₅H₁₁NO₂

   

• Molecular Weight 117.15

   

•  MDL number MFCD00005947

   

•  PubChem Substance ID 2485566

a pretreatment for techno-economical study of ethanol and biogas production from spruce wood